Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B W. Vogel & M. Büttner GmbH und gemeint sind hier die
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Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B W. Vogel & M. Büttner GmbH und gemeint sind hier dieIn his thesis, Xiaoyu Sun conducts the first total synthesis of all possible stereoisomers of plakortide E and also confirms the absolute configuration of natural plakortide E. Xiaoyu Sun subsequently converts Plakortide E methyl ester to plakortone B in a biomimetic conversion. Construction and functionalization of cyclic peroxides are notoriously difficult due to the very low O O bond dissociation energy. Plaktoride E is isolated from the Jamaican
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